198048-100ML Display Image

Trimethylaluminum solution, 2.0 M in toluene

Code: 198048-100ML D2-231

Application

Used in a recently reported Al-catalyzed oxidation based on Oppenauer chemistry providing excellent yields of aldehydes and ketones. As a (1:1) complex with binol...


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Your Price
£80.50 100ML

Application

Used in a recently reported Al-catalyzed oxidation based on Oppenauer chemistry providing excellent yields of aldehydes and ketones. As a (1:1) complex with binol catalyzes the dynamic kinetic resolution of secondary alcohols with Novozym 435.

Trimethylaluminum solution can be used as a reagent in the synthesis of: Polyhydroxylated cyclohexanes by stereoselective rearrangement of unsaturated glycosides. Partially hydrolyzed trimethylaluminum (PHT) catalyst for the polymerization of olefins. Methyl benzene by methylation of anisole derivatives using nickel-1,3-dicyclohexylimidazol-2-ylidene catalyst system.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Packaging

4×25, 100, 800 mL in Sure/Seal™

1 L in Sure/Seal™

8, 18 L in Kilo-Lab™

View returnable container options.

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

concentration2.0 M in toluene
density0.81 g/mL at 25 °C
formliquid
InChI keyJLTRXTDYQLMHGR-UHFFFAOYSA-N
InChI1S/3CH3.Al/h3*1H3;
Quality Level200
SMILES stringC[Al](C)C
Cas Number75-24-1
Hazard Class4.3
Un Number3399
Pack GroupI
This product has met the following criteria: